高压下聚苯胺的结构和电性能研究

 以金刚石压腔高压装置为工具，用Ⅱ型金刚石作压砧兼红外窗口，对本征态聚苯胺进行了高压（0~8.4 GPa）就位红外光谱测试。结果表明：在4.8~5.2 GPa压力区间，代表醌环振动的吸收峰相对代表苯环振动的吸收峰变小，表明聚苯胺在此压力区间结构上发生了显著变化，且这种变化是不可逆的。聚苯胺的高压（0~14.5 GPa）电阻测量结果表明：当压力小于7.5 GPa时，电阻随压力升高而显著降低，据此认为聚苯胺为电子性导电物质；在7.5 GPa处电阻出现极小值，然后又缓慢升高，至10 GPa后基本不变。推测聚苯胺电阻极小值是由结构变化引起的。至于红外光谱与电阻测量结果反映聚苯胺结构变化的压力值不一致，可能是由于测试条件不同所致。     

Crystal structure and magnetic ordering of RNi Si compounds

The element distributions and the magnetic ordering behaviour of compounds RNi₁₀Si₂ (R = Tb, Dy, Ho, Er, Tm) have been studied by neutron powder diffraction down to temperatures of 1.6 K. The compounds crystallize in an ordered variant of the ThMn₁₂ structure type in the tetragonal space group P4/nmm. An ordered 1:1 distribution of Ni and Si on sites 4d and 4e, respectively, corresponds to a modulation vector [0, 0, 1] with respect to the space group I4/mmm of the ThMn₁₂ structure. TbNi₁₀Si₂ orders antiferromagnetically below T _N = 4.5 K with a magnetic propagation vector of [0, 0, 1/2]. The magnetic Tb moments, 8.97(2) /Tb atom at 1.6 K, are aligned along the c-axis. The Ni sites in TbNi₁₀Si₂ do not carry any ordered magnetic moments. The compounds with R = Dy, Ho, Er, and Tm are paramagnetic down to 1.6 K and 3.0 K, respectively. Received 10 July 2002 / Received in final form 12 September 2002 Published online 29 October 2002     

气体栓塞演示实验

利用自制实验装置直观地演示了水在细管中流动，若有气泡存在时产生的气体栓现象。     

Application of stochastic optimal control to the suboptimal design of thrust-mass profiles

Stochastic optimal control techniques are applied to compare the performance of identical medium-range air-to-air missiles which have different thrust-mass profiles. The measure of the performance is the probability of reaching a lock-on-point with a favorable range of guidance and flight parameters, during a fixed time interval [0,t _f ], given that, during the flight, the trajectories of the missile are subjected to a variety of constraints including dynamic pressure constraints.     

同位网格上不可压流动的反欠松弛压力修正算法

本文提出了同位网格上的不可压流动压力修正算法,其中压力修正值由压力方程所求得。设计了分离式的动量插值方法,有效地避免了松弛因子对计算结果的影响和不合理压力场的出现。提出了构造压力方程的反欠松弛方法,该方法建立了稳定和加速计算收敛的一般途径。对经典算例的计算得到了满意的结果。     

简析"静止液体内部压强公式验证"实验的设计策略

“静止液体内部压强公式验证”在现行教材中有两种实验方法。通过分析实验的设计策略，说明其作用、效果及操作上的困难，指出合理的与不合理诸因素，从而提出改进实验的方法，化难为易，提高实验教学效果。     

The Properties of Light Pressure Force with High Order in Laser Fields

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Acoustic characterization and prediction for fan-duct-plenum-room integrations

This paper investigates mutual influence of duct and room acoustics in the whole fan-duct-plenum-room integrations. Applying the parametric design language of finite element software ANSYS (APDL), dimensional and positional influence on system acoustics has been studied. Models with different room dimensions, duct lengths, duct cross-sections, duct locations, duct discharges and duct elbow were constructed, and their characteristics were compared qualitatively. Results show that small rooms, short ducts, large duct cross-sections and bell mouth duct discharges help to increase room sound pressure levels (SPLs); SPLs in ducts and plenums are sensitive to duct dimensions and duct discharge types but insensitive to duct locations and room dimensions; duct elbows have relatively indistinct acoustic influence in each component. Based on the calculation results, a semi-experimental method was proposed for simply and approximately evaluating indoor acoustic spectra of fan-duct-plenum-room integrations, then an example was used to demonstrate the prediction process. Finally, by adopting several ideal models, sound field constitutions, duct and room wall admittances and duct end reflection were explored quantitatively. This study may give a detailed understanding of fan-duct-plenum-room acoustics for researchers, also it might provide a new, simple and approximate prediction method for professionals to evaluate and improve fan-ducted acoustics.     

Assessing contaminated hydrogen peroxide for safe storage and transportation using the FTAI

Hydrogen peroxide is a very versatile oxidizing agent, and it is also environmentally compatible considering that the products of its exothermic decomposition are oxygen and water.When kept in a clean temperature-controlled environment, the self-reaction (decomposition) rate is extremely low. However, it is well known that even a small amount of contamination will dramatically increase the reaction rate. This paper describes the use of the fast thermal activity interpreter (FTAI) instrument to examine the chemical reactivity of commercially available 50% hydrogen peroxide at two different temperatures (30 and 40°C) both with and without contamination. The results show that at 30°C a small amount of rust (330 ppm) increases the reaction rate of 50% hydrogen peroxide by a factor of 50. When the temperature is increased to 40°C, the reaction rate is further increased by almost a factor of four. The implication for reactivity management is that at this contamination level most practical vessel sizes would require emergency venting capability. An evaluation was then performed to determine the emergency venting requirement for the safe transportation or storage of the contaminated hydrogen peroxide. It was determined that for quantities of the material less than 5 gallons, conventional breather vents would be sufficient to accommodate the gas evolved. However, for larger quantities, a safety relief device would be needed. For example, for a 400-gallon tote bin at 40°C the required minimum vent area is estimated to be 4.3 in², corresponding to a minimum vent diameter of 2.3 inches.     

Bubble point pressure estimates from Gibbs ensemble simulations

Bubble pressure points of ethanol–1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea refrigerant) mixtures from the third Industrial Fluid Properties Simulation Challenge are computed using publicly available molecular simulation software. Several published force fields are compared against the known answers provided in the contest guidelines and the best force fields are used to make predictions for the unknown results.